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Ion Cyclotron Resonance Spectrometry Ii

2nd International Symposium : Papers

Ion Cyclotron Resonance Spectrometry Ii - ISBN: 9783540119579
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Bindwijze: Boek
Genre: Theoretische natuurkunde
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Beschrijving

In this volume 28 papers are presented. They cover all the fields studied with ion cyclotron resonance today, including reviews on important fields as well as short contributions on special topics. This report is devided into four parts: 1. Detailed studies on simple molecules, 2. Systematic studies of the ion chemistry, 3. Spectrometer development and 4. Theory. The plan to edit a progress report of the complete field was projected at the 2nd International Symposium on Ion Cyclotron Resonance Spectrometry, held at the Akademie der Wissenschaften und der Literatur, Mainz, March, 1981. Most of the contributions were written in late 1981 or in 1982. Hermann Hartmann Akademie der Wissenschaften und der Literatur Mainz Karl-Peter Wanczek Institut fUrphysikalische und theoretische Chemie Universitat, Frankfurt Acknowledgements The editors gratefully acknowledge support of the Symposium by the Stiftung Volkswagenwerk and the Fonds der Chemischen Industrie. The editors want to take the opportunity to thank H. Otten, President, Akademie der Wissenschaften und der Literatur, for the hospitality all the participants of the Symposium enjoyed. IV Delegates attending the 2nd International Symposium on Ion Cyclotron Reso nance Spectrometry, Akademie der Wissenschaften und der Literatur, Mainz (numbers refer to the photograph) 26. D. Parent 1. M. B. Comisarow 2. 27. R. T. McIver, Jr.

Details

Titel: Ion Cyclotron Resonance Spectrometry Ii
Mediatype: Boek
Taal: Engels
Aantal pagina's: 540
Uitgever: Springer-verlag Berlin And Heidelberg Gmbh & Co. Kg
Plaats van publicatie: 04
NUR: Theoretische natuurkunde
Afmetingen: 235 x 155
Gewicht: 910 gr
ISBN/ISBN13: 9783540119579
Intern nummer: 24380107

Inhoudsopgave

Table of Content.- Topics in Ion Photodissociation.- 1. Introduction.- 2. Experimental Aspects.- 3. Ion Spectroscopy.- 4. Ion Structure Studies.- 4.1.Chloropropene Ions.- 4.2.Benzyl Chloride Ion.- 4.3.Dien-Ion Rearrangements.- 5. Photofragmentation.- 6. Multi photon Photochemistry.- 6.1. Two-Photon Dissociation and Collisional Relaxation.- 6.2. Two-Laser Photodissociation.- References.- Ion Structures and Relaxation of Vibrationally Excited Ions as Studied by Photodissociation.- 1. Introduction.- 1.1. Photodissociation of Ions of One Structural Form.- 1.2. Photodissociation of a Mixture of Ions of Equal Mass.- 1.3. Relaxation of Ions Produced with a Large Amount of Internal Energy.- 1.4. Multiphoton Processes.- 2. Ion Structures.- 2.1. C6H6O·+ Ions.- 2.2. Alkene Ions.- 3. Relaxation in Single Photon Precesses, C2H4·+ Ions from Ethylene Oxide and 1,3-Dioxolane.- 4. Two Photon Processes.- References.- Infrared Photochemistry of Gas Phase Ions.- 1. Introduction.- 2. Experimental Section.- 3. Results.- 3.1. Multiphoton Dissociation of Ions with Low Intensity cw Infrared Radiation.- 3.1.1. Summary of Multiphoton Dissociation Results.- 3.1.2. Variation of Photodissociation Yield with Laser Wavelength.- 3.1.3. Effect of Collisions on Photodissociation Yield.- 3.1.4. Variation of Photodissociation Yield with Laser Irradiance.- 3.2. Applications of Multiphoton Dissociation.- 3.2.1. Multiphoton Excitation as a Probe of Bimolecular and Unimolecular Reaction Energetics.- 3.2.2. Multiphoton Dissociation as a Probe of Molecular Relaxation Rates.- 3.2.3. Multiphoton Dissociation as a Probe of the Vibrational Quasi-Continuum.- 3.2.4. Isotopic Selectivity in Multiphoton Dissociation.- 3.2.5. Isomeric Selectivity in Multiphoton Dissociation.- 3.3. Multiphoton Electron Detachment from Negative Ions.- 3.4. Selective Enhancement of Bimolecular Reaction Rates Using Low Intensity cw Laser Radiation.- 4. Prognosis.- References.- Study of Atomic Metal Ions Generated by Laser Ionization.- 1. Metal Ion Chemistry.- 2. Kinetic Energy of Laser Generated Ions. A Comparison of Techniques.- 3. Fourier Transform Mass Spectrometry.- References.- Gas-Phase Atomic Metal Cations. Ligand Binding Energies, Oxidation Chemistry and Catalysis.- 1. Introduction.- 2. Ligand Dissociation Enthalpies.- 3. Cooperative Bonding Effects.- 4. Metal Oxide Cations.- 5. Catalysis 135.- References.- Transition Metal Ions in the Gas Phase.- 1. Introduction.- 2. Electronically Excited Cr+.- 3. Reactions of Diatomic Metal Ions.- 4. Reactions of Cyclic Ketones.- References.- Elucidation of the Transfer Mechanism in Ion-Molecule Reactions by ICR.- 1. Introduction.- 2. Experimental.- 3. Results and Discussion.- 4. Conclusion.- References.- Equilibrium Studies of Electron Transfer Reactions.- 1. Introduction.- 2. Electron Affinities: Theoretical Considerations.- 3. Experimental Methods for Measuring Electron Affinities.- 4. Pulsed ICR Techniques for Negative Ions.- 5. Results for Equilibrium Electron Transfer Equilibria.- 6. Discussion 179.- References.- ICR Study of Negative Ions Produced by Electron Impact in Water Vapor.- 1. Introduction.- 2. Experimental.- 3. Results.- 4. Discussion.- References.- Reactions with Alkoxide Anions.- 1. Introduction.- 2. Experimental.- 3. Results.- 4. Discussion.- 4.1. Internal Energy.- 4.2. Enolate Formation.- 4.3. CID Experiments.- 4.4. Labelled Reactants.- References.- A Fourier Transform Ion Cyclotron Resonance Study of Negative Ion-Molecule Reactions of Phenyl Acetate, Phenyl Trifluoroacetate and Acetanilide.- 1. Introduction.- 2. Results and Discussion.- 2.1. Phenyl trifluoroacetate.- 2.1.1. Primary Ions.- 2.1.2. H2O/C6H5OCOCF3.- 2.2. Acetanilide.- 2.3. Phenyl acetate.- 2.3.1. H2O/C6H5OCOCH3.- 2.3.2. H2O/CH3OCH3/C6H5OCOCH3.- 3. Conclusion.- 4. Experimental Section.- References.- Site of Protonation in Gaseous Five-Membered Ring Systems C4H4X(X=NH,O,S,CH2).- 1. Introduction.- 2. Experimental.- 3. Results and Discussion.- 3.1. Equilibrium Proton Af

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