Fluorinated Ionomers

A Guide To Engineers And Scientists Working In Electrochemistry, The Fuel Cell Industry And Other Areas Of Application. It Covers The Techniques Involved In The Growing Range Of Applications For Fluorinated Ionomers, Including Fuel Cells, Batteries And Drug Delivery.

Titel:	Fluorinated Ionomers
Auteur:	Grot, Walther
Mediatype:	Boek
Bindwijze:	Gebonden
Taal:	Engels
Druk:	2
Aantal pagina's:	312
Uitgever:	William Andrew Publishing
Plaats van publicatie:	01
NUR:	Laboratoriumtechniek
Afmetingen:	229 x 152 x 28
Gewicht:	907 gr
ISBN/ISBN13:	9781437744576
Intern nummer:	17804129

Plastics Design Library

ix

PDL Fluorocarbon Series Editor's Preface

xi

Preface

xiii

Acknowledgements

xv

1 Introduction

1

(4)

1.1 Polymers

1

(1)

1.2 Physical Shapes

2

(3)

References

3

(2)

2 History

5

(6)

References

9

(2)

3 Manufacture

11

(38)

3.1 Introduction

11

(1)

3.2 Perfluorinated Ionomers

11

(15)

3.2.1 Monomer Synthesis

12

(14)

3.3 Polymerization

26

(4)

3.4 Fabrication

30

(4)

3.5 Hydrolysis and Acid Exchange

34

(1)

3.6 Finishing and Testing

35

(2)

3.7 Liquid Compositions

37

(2)

3.7.1 Film Casting

38

(1)

3.8 Fluorinated Ionomers with Phosphonic or Sulfonyl Imide Functional Groups

39

(1)

3.9 Partially Fluorinated Ionomers

40

(2)

3.9.1 Grafting of Non-fluorinated Monomers on Fluorinated Films

40

(1)

3.9.2 Polymerization of Partially Fluorinated Monomers

41

(1)

3.9.3 Fluorinated Anion Exchange Polymers

42

(1)

3.10 Composite Materials of Ionomers and Inorganic Oxides

42

(2)

3.11 Composite Materials of Ionomers and a Porous Matrix

44

(1)

3.12 Remanufactured Membranes

45

(4)

References

46

(3)

4 Properties

49

(32)

4.1 Properties of the Precursor Polymers

49

(3)

4.2 Properties of the Ionic Forms

52

(16)

4.2.1 Swelling in Water and Other Solvents

59

(7)

4.2.2 Wetting and Contact Angle

66

(2)

4.2.3 Solubility of Gases in Fluorinated Ionomers

68

(1)

4.3 Morphology

68

(6)

4.3.1 Morphology and Properties of Liquid Compositions

70

(4)

4.4 Transport Properties

74

(1)

4.4.1 Transport Driven by an Electric Current

74

(1)

4.4.2 Transport Driven by a Concentration Difference

75

(1)

4.5 Optical Properties

75

(1)

4.6 Thermal Properties

76

(1)

4.7 Stability

76

(5)

References

78

(3)

5 Applications

81

(76)

5.1 Electrolysis

81

(59)

5.1.1 Introduction, Electrolytic Cells

81

(1)

5.1.2 NaCl Electrolysis

82

(35)

5.1.3 Related Technology: HC1 electrolysis

117

(2)

5.1.4 The Older Technologies: Mercury and Asbestos

119

(4)

5.1.5 Electrolysis of Other Chlorides, Including Tetramethyl Ammonium Chloride

123

(2)

5.1.6 Potassium Gold Cyanide and Potassium Stannate

125

(2)

5.1.7 Salt Splitting

127

(3)

5.1.8 Chromic Acid Regeneration

130

(3)

5.1.9 Nickel-Zinc Plating

133

(1)

5.1.10 Persulfuric Acid and Persulfates

133

(1)

5.1.11 Electro-winning of Metals

133

(1)

5.1.12 Water Electrolysis (Including the Production of Ozone or Hydrogen Peroxide)

134

(3)

5.1.13 Other Electrolytic Applications

137

(3)

5.2 Sensors and Actuators

140

(4)

5.3 Dialysis

144

(2)

5.4 Gas and Vapor Diffusion

146

(4)

5.5 Protective Clothing

150

(1)

5.6 Catalysis

151

(6)

References

153

(4)

6 Fuel Cells and Batteries

157

(28)

6.1 Introduction

157

(5)

6.2 Operating Parameters

162

(3)

6.3 Lonomer Stability

165

(8)

6.3.1 Minimizing Polymer Degradation

172

(1)

6.4 Direct Methanol Fuel Cells (DMFCs)

173

(3)

6.5 Manufacture of MEAs

176

(1)

6.6 Rechargeable Flow Through Batteries

177

(8)

References

182

(2)

Prijs:	€ 176,00
Levertijd:	3 tot 5 werkdagen
Bindwijze:	Boek, Gebonden
Genre:	Laboratoriumtechniek

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